THE CATHODIC CAGE PLATFORM IN SURFACE ENGINEERING

Authors

  • Renan Matos Monção Universidade Federal do Piauí – Pró-Reitoria de Pós-Graduação – Programa de Pós-Graduação em Ciências e Engenharia dos Materiais – Teresina (PI), Brazil.
  • Gabriely Gonçalves Lima Universidade Federal do Piauí – Pró-Reitoria de Pós-Graduação – Programa de Pós-Graduação em Ciências e Engenharia dos Materiais – Teresina (PI), Brazil.
  • Thercio Henrique de Carvalho Costa Universidade Federal do Rio Grande do Norte – Centro de Tecnologia – Departamento de Engenharia Mecânica – Natal (RN), Brazil.
  • Romulo Ribeiro Magalhães de Sousa Universidade Federal do Piauí – Pró-Reitoria de Pós-Graduação – Programa de Pós-Graduação em Ciências e Engenharia dos Materiais – Teresina (PI), Brazil.

DOI:

https://doi.org/10.17563/rbav.v44i1.1271

Keywords:

Cathodic cage, Plasma deposition, Surface engineering

Abstract

This review summarizes the development of cathodic cage plasma nitriding (CCPN) and cathodic cage plasma deposition (CCPD) techniques. CCPN was introduced to eliminate issues in direct current plasma nitriding (DCPN), such as the edge effect, by isolating the sample at a floating potential and using radiative heating. The process was further adapted for CCPD, in which the cage serves as a sputtering target (e.g., Ti, graphite, Mo, Hastelloy) for the deposition of ceramic and metallic films. Combining nitriding pretreatment with CCPD resulted in duplex treatments that establish a hardness gradient and enhance film adhesion. The most recent advance is cathodic cylinder plasma deposition (CCyPD), which employs compacted powder targets (such as MoS2 or metal oxides) for composite film deposition and in situ oxide reduction. The review traces the evolution from process improvement to a versatile platform for surface engineering.

Downloads

Download data is not yet available.

References

1. Alves C, Araújo FO, Ribeiro KJB, Costa JAP, Sousa RRM, Sousa RS. Use of cathodic cage in plasma nitriding. Surf Coat Technol. 2006;201(6):2450-2454. https://doi.org/10.1016/j.surfcoat.2006.04.014

2. Sousa RRM, Araújo FO, Ribeiro KJB, Mendes MWD, Costa JAP, Alves C. Cathodic cage nitriding of samples with different dimensions. Mater Sci Eng.: A. 2007;465(1-2):223-227. https://doi.org/10.1016/j.msea.2007.03.007

3. Sousa RRM, Araújo FO, Gontijo LC, Costa JAP, Alves C. Cathodic cage plasma nitriding (CCPN) of austenitic stainless steel (AISI 316): influence of the different ratios of the (N 2/H 2) on the nitrided layers properties. Vacuum. 2012; 86(12): 2048-2053. https://doi.org/10.1016/j.vacuum.2012.05.008

4. Ribeiro KJB, Sousa RRM, Araújo FO, Brito RA, Barbosa JCP, Alves C. Industrial application of AISI 4340 steels treated in cathodic cage plasma nitriding technique. Mater Sci Eng.: A. 2008;479(1-2):142-147. https://doi.org/10.1016/j.msea.2007.06.033

5. Sousa RRM, Sato PS, Viana BC, Alves C, Nishimoto A, Nascente PAP. Cathodic cage plasma deposition of TiN and TiO2 thin films on silicon substrates. J Vac Sci Technol. A: Vac Surf Films. 2015;33(4). https://doi.org/10.1116/1.4919770

6. Abreu LHP, Naeem M, Monção RM, Costa THC, Díaz-Guillén JC, Iqbal J, et al. The effect of cathodic cage plasma TiN deposition on surface properties of conventional plasma nitrided AISI-M2 steel. Metals (Basel). 2022;12(6). https://doi.org/10.3390/met12060961

7. Lima LLF, Libório MS, Neto JFM, Coan KS, Rossino LS, Sousa RRM, et al. Plasma deposition of solid lubricant coating using AISI1020 steel cathode cylinders technique. Mater Res. 2023;26. https://doi.org/10.1590/1980-5373-MR-2022-0623

8. Medeiros Neto JF, Lima LLF, Vieira PS, Costa BT, Libório MS, Queiroz JCA, et al. Plasma deposition from cathodic cylinders: a technology for reduction of metallic oxides and deposition of wear-resistant films. Surf Coat Technol. 2024; 488. https://doi.org/10.1016/j.surfcoat.2024.131027

9. Monção RM, Júnior EAA, Bandeira RM, Abreu Lima CD, Luz Lima C, Feitor MC, et al. Evaluation of corrosion resistance of thin films formed on AISI 316L Steel by plasma using hastelloy as cathodic cage. Phys Status Solidi (A) Appl Mater Sci. 2021;218(10). https://doi.org/10.1002/pssa.202000578

10. Sousa RRM, Costa THC, Costa JAP, Santos FEP, Nascimento IO, Souza IA, et al. Cathodic cage plasma deposition of DLC film on D2 steel substrate. 2019. Available from: https://www.rroij.com/open-access/cathodic-cageplasma-deposition-of-dlc-film-on-d2-steelsubstrate.php?aid=87535

11. Naeem M, Fortaleza VC, Serra PLC, Lima CL, Costa THC, Sousa RRM, et al. Synthesis of molybdenum oxide on AISI-316 steel using cathodic cage plasma deposition at cathodic and floating potential. Surf Coat Technol. 2021; 406. https://doi.org/10.1016/j.surfcoat.2020.126650

12. Silva LP, Naeem M, Díaz-Guillén JC, Brito MCS, Monção RM, Silva LGL, et al. Enhanced surface properties of 1080 eutectoid steel by cathodic cage plasma TiN deposition. JOM. 2025;77(2):539-548. https://doi.org/10.1007/s11837-024-06949-w

13. Silva LP, Libório MS, Sousa EM, Silva LGL, Monção RM, Brito MCS, et al. Enhancing wear resistance of AISI 1045 steel through duplex plasma treatment with vanadium cage. JOM. 2025;77(2):631-639. https://doi.org/10.1007/s11837-024-07020-4

14. Naeem M, Torres AVR, Serra PLC, Monção RM, Junior CAA, Rossino LS, et al. Combined plasma treatment of AISI-1045 steel by hastelloy deposition and plasma nitriding. J Build Eng. 2022;47. https://doi.org/10.1016/j.jobe.2021.103882

15. Naeem M, Shafiq M, Zaka-ul-Islam M, Bashir MI, Díaz-Guillén JC, Lopez-Badillo CM, et al. Novel duplex cathodic cage plasma nitriding of non-alloyed steel using aluminum and austenite steel cathodic cages. J Alloys Compd. 2017;721:307-311. https://doi.org/10.1016/j.jallcom.2017.06.004

16. Silva LGL, Brito MCS, Sousa EM, Nolêto BJS, Silva LP, Costa THC, et al. Effect of the vanadium layer on the wear resistance of the 1050 aluminum alloy coated by cathodic cage plasma deposition. Stud Eng Exact Sci. 2024; 5(2): e7377. https://doi.org/10.54021/seesv5n2-155

17. Libório MS, Praxedes GB, Lima LLF, Nascimento IG, Sousa RRM, Naeem M, et al. Surface modification of M2 steel by combination of cathodic cage plasma deposition and magnetron sputtered MoS2-TiN multilayer coatings. Surf Coat Technol. 2020;384. https://doi.org/10.1016/j.surfcoat.2019.125327

18. Sousa ME, Brito MC, Silva LP, Nolêto BJ, Silva LG, Monção RM, et al. deposition of metal oxides (Mo-Cu-Ti-Fe) using the cathodic cage deposition technique. Int J Adv Eng Technol. 2024;17:593-602. https://doi.org/10.5281/zenodo.14731275

19. Sampaio WRV, Brito MCS, Serra PLC, Monção RM, Sousa EM, Nolêto BJS, et al. Incorporation of TiO2 nanoparticles in thin films deposited on AISI 304 stainless steel using the cathodic cage technique: a preliminary study. Int J Adv Eng Technol. 2024;17:528-541. https://doi.org/10.5281/zenodo.14172994

20. Santos RSM, Naeem M, Silva AL, Medeiros Aires M, Sousa RRM, Carvalho Costa TH, et al. Novel synthesis of zinc oxide on cotton fabric by cathodic cage plasma deposition for photocatalytic and antibacterial performance. Int J Mol Sci. 2024;25(18). https://doi.org/10.3390/ijms251810192

Downloads

Published

2025-12-16