DIAMOND-LIKE CARBON FILMS: IMPROVED PROPERTIES AND NEW APPLICATIONS

Authors

  • Luis Francisco Bonetti Clorovale Diamantes – Research, Development and Innovation – Torrão de Ouro – São José dos Campos (SP), Brazil.
  • Fernanda Roberta Marciano Universidade Federal do Piauí – Physics Department – Teresina (PI), Brazil.
  • Gabriely Gonçalves Lima Universidade Federal do Piauí – Physics Department – Teresina (PI), Brazil.
  • Renan Matos Monção Universidade Federal do Piauí – Physics Department – Teresina (PI), Brazil.
  • Luz Stefany Murcia Correa Universidade Federal de São Paulo – Department of Engineering and Materials Science – São José dos Campos (SP), Brazil.
  • Elver Juan de Dios Mitma Pillaca Instituto Nacional de Pesquisas Espaciais – Department of Applied Research and Technological Development – São José dos Campos (SP), Brazil.
  • Evaldo José Corat Instituto Nacional de Pesquisas Espaciais – Department of Applied Research and Technological Development – São José dos Campos (SP), Brazil.
  • Vladimir Jesus Trava-Airoldi Instituto Nacional de Pesquisas Espaciais – Department of Applied Research and Technological Development – São José dos Campos (SP), Brazil.

DOI:

https://doi.org/10.17563/rbav.v44i1.1278

Keywords:

DLC films, Growth process, PECVD techniques, Properties, Applications

Abstract

Since 1972, diamond-like carbon (DLC) thin films have attracted great scientific and technological interest due to their unique properties, notably the high adhesion on metallic and non-metallic substrates, allowing them to expand their applications to areas such as space and biological. DLC films can be obtained by various techniques, such as physical vapor deposition, ion beam-assisted deposition, and plasma enhancement chemical vapor deposition (PECVD). This review focused on the studies of the Diamond and Related Materials Research Group, which compared various techniques and selected direct current (DC) pulsed PECVD for its low cost and versatility. The studies focused on determining the coating parameters such as adhesion, hardness, friction, wear  resistance, biocompatibility, structural stresses, and scalability. Next, the group improved the DC pulsed PECVD with the introduction of the concept of ion and electron confinement. This innovative method has made it possible to obtain better plasma density at low pressures, improving the characteristics of the film. The non-collision growth process resulted in a harder DLC, with better adhesion, less wear, and maintained biocompatibility. The system has proven to be effective, cost-effective, easy to use, and scalability even for complex geometries

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2025-12-16